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4-(Trifluoromethyl) nicotinic acid Reference Standard | Chem Service | Greyhound Chromatography the UK's Leading Chromatography Supplier

4-(Trifluoromethyl) nicotinic acid Reference Standard 

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4-(Trifluoromethyl) nicotinic acid
Alternative Names: TFNA (FLONICAMID METABOLITE), 4-(TRIFLUOROMETHYL)NICOTINIC ACID
Product Code: MET-11976A-100MG

Triclosan
Alternative Names: TFNA (FLONICAMID METABOLITE), 4-(TRIFLUOROMETHYL)NICOTINIC ACID'
Product Code: N-13076-100MG

Metamifop
Product Code: N-13084-25MG

Fthalide
Product Code: N-13085-10MG

Triclosan Solution
Product Code: S-13076M1-1ML

2,2',4,4',6-Pentabromodiphenyl Ether BDE-100 Solution
Product Code: S-13123K0-1ML

2,2',3,4,4',5,6-Heptabromodiphenyl Ether (BDE-181) Solution
Product Code: S-13128K0-1ML

What's New from Chem Service 

Chem Service Certified Reference Standards

  What's new from Chem ServiceChem Service Pesticide Catalogue Image      Chem Service General Catalogue Image

 

Established in 1962 Chem Service is the largest independent supplier of Analytical Reference Materials and the original source of small quantities of organic chemicals. Chem Service also has over 2,000 Pesticide Standards, including Pesticide Standards for Cannabis in its catalogue.  Chem Service offers Custom made Standards manufactured to your specific requirements, all standards are accredited to ISO 17043:2016; ISO/IEC 17025:2005; ISO 9001:2015 Quality Management System.

Over 95% of Chem Services’ neat Standards Grade materials have a purity of 98.0% or greater.

Chem Services’ worldwide customers are found in the chemical, government, food quality, agricultural and life science research communities.

 

Pesticide Reference Standards recently added to our website: 

2,3',4',5-tetrabromodiphenyl ether(BDE 70) Solution (CAS # 446254-39-3)

Chemical Structure image

BUY HERE

Part #:S-14273K0-1ML
CAS: 446254-39-3 

o,o,o-Tripropyl thiophosphate (CAS # 2272-08-4)

Chemical Structure image

BUY HERE 

Part #:MET-11103A-25MG
CAS: 2272-08-4

 

Chemical Structure image

BUY HERE

Part #:N-14272-50MG
CAS: 304911-98-6

2,6-Dibromobiphenyl ether (BDE 10) Solution (CAS# 51930-04-2)

Chemical Structure Image

BUY HERE

Part #:S-14271K0-1ML
CAS: 51930-04-2
Classification: Polybrominated diphenyl ether
Uses: Flame retardant 
 
Chem Service Product Image
 
Part #:MET-11963F-50MG
CAS: 56236-69-2
 

Oxathiapiprolin (CAS# 1003318-67-9)

Chemical Structure Image

BUY HERE

Part Number : N-14266-10MG

CAS#:  1003318-67-9

Chemical formula: C24H22F5N5O2S

Pesticide type: Fungicide

Substance group: Piperidinyl thiazole isoxazoline

Mode of action: Systemic, preventative with residual disease control. It acts via an oxysterol binding protein.

2-Bromodiphenyl ether (BDE 1) Solution (CAS# 7025-06-1) 

Chemical Structure Image BUY HERE

Part #:S-14267K0-1ML
CAS: 7025-06-1
Empirical Formula:  C12H9BrO
Molecular Weight: 249.10

 

Chlorantraniliprole (CAS # 500008-45-7) 

Chemical Structure Image

BUY HERE 

Part #: N-11422-25MG 

Cas: 500008-45-7 

Molecular Formula: C18H14BrCl2N5O2 

Pesticide type: Insecticide 

Substance group: Anthranilic diamide 

Mode of action: Exhibits larvicidal activity as an orally ingested toxicant by targeting and disrupting the Ca2+ balance; Ryanodine receptor (Group 28)

Chlorantraniliprole Solution (CAS # 500008-45-7)

Chemical Structure Image

BUY HERE

Part Number: S-11422A1-1ML

Cas: 500008-45-7

 

Please visit our website to see pricing for Chem Service products. You may benefit from a discount to the prices shown if you are placing orders for multiple items, please contact sales@greyhoundchrom.com for a quotation.  Please note you will be required to register to the website in order to view prices.

Multilingual MSDS avaliable, please email us to find out more using info@greyhoundchrom.com  

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Forensic Analysis Reference Standards | Chem Service | Greyhound Chromatography
New Lipstick Analysis Technique May Help Police Track Down Criminals | Greyhound Chromatography
Certified Reference Standards | Chem Service | Greyhound Chromatography
Certified Reference Standards
Arachidic acid Methylester (CAS # 1120-28-1) Botanical Reference Standards | Greyhound Chromatography
Extrasynthese Arachidic acid methylester (CAS # 1120-28-1) Analytical Reference Standards | Greyhound Chromatography
Betulinic Acid Methylester (CAS # 131279) Botanical Reference Standards | Extrasynthese | Greyhound Chromatography
Extrasynthese Betulinic acid methylester (CAS # 131279) Analytical Reference Standards | Greyhound Chromatography
(+)-L-Alliin (CAS # 556-27-4) Botanical Reference Standard | Extrasynthese | Greyhound Chromatography
Alliin (CAS # 556-27-4) Extrasynthese Analytical Reference Standard | Greyhound Chromatography Certified Reference Standards and Materials
Are there Pesticides in Tea? | Chem Service | Greyhound Chromatography

Pesticides in your Tea?

Green tea image

Tea is an enormously popular crop that has been a critical part of commerce and culture for centuries. Not only is tea the most popular drink after water across the globe, it's hugely popular in the U.S. In 2014, Americans drank about 3.6 billion gallon of tea, hot or iced, which equals about 80 billion servings, according to the Tea Association of the USA.

The segment of the population who drinks the most tea are millennials – 87 percent drink tea – meaning that its importance in the U.S. will likely only continue to grow. While more than 158 million people drink tea each day in the U.S., much of the tea is grown outside its borders. The U.S. is second only to Russia as the largest importer of tea, according to Tea USA.

If you're considering getting into tea farming, you're curious about the pests on plantations or you want to know which chemicals are in your tea cup, learn more about how and why pesticides are used in tea production.

Tea plantations are heaven for pests

A 2008 study from Mizoram Central University in India, which was published in the Journal of Environmental Biology, explained that the way tea is typically grown creates a great situation for pests. Tea is a perennial that is often grown in monoculture, meaning that there aren't other crops grown along with it. This, along with the climates that best facilitate tea growth have created "favorable conditions" for pests, the study explained.

Many of the world's top tea producers – China, India, Sri Lanka, Kenya, Turkey – have been growing the crop for centuries. However, most farmers have been shifting to a pest control method heavier toward using chemical pesticides to fight off these plentiful pests. Over time many tea pests have developed resistance to some pesticides and the public has become upset by the pesticides that have been commonly used, such as DDT, endosulfan, dicofol and ethion. The 2008 report noted that these concerns, along with the cost of treating tea have had an impact.

"The growing concern about the pesticide residue in made tea, its toxicity hazards to consumers, the spiraling cost of pesticides and their application have necessitated a suitable planning which will ensure a safe, economic as well as effective pest management in tea," the report explained.

Pesticide residues in common brands

Since 2008, many people have examined the amounts of pesticides that are found in the tea that actually makes it into millions of people's homes. A Canadian Food Inspection Agency study that was published in the Journal of Agricultural and Food Chemistry in 2014 found that many pesticides not only made it into people's cupboards but also to the tea itself.

"The pesticide residues were likely transferred from tea leaves to brewed tea during the brewing process, and may therefore pose a risk to consumers," the study concludes, according to the Canadian Broadcasting Corporation. Many of the world's most common pesticides were found in quantities less or far less than 1 part per million. Acetamiprid (also sold as Mospilan®Saniprid®; Acer®Aspilan®), chlorpyrifos,   also sold as  O.O-Diethyl-O-[3.5.6-trichloro-2-pyridyl]-phosphorothioateDursban®TrichlorpyrphosPyrinex®, thiacloprid, also sold as (3-((6-Chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)cyanamide imidacloprid; also sold as Admire®Confidor®Gaucho®Merit®; 1-[(6-Chloro-3-pyridinyl)methyl]-N-nitro-2-imidazolidiniminedicofol; also sold as Kelthane (TM) ; 4.4'-Dichloro-a-[trichloromethyl]benzhydrol1.1-Bis(p-chlorophenyl)-2.2.2-trichloroethanol methomylendosulfan sulfate; also sold as 6.7.8.9.10.10-Hexachloro-1.5.5a.6.9.9a-hexahydro-6.9-methano-2.4,  and carbendazim; also sold as  2-(Methoxycarbonylamino)-benzimidazoleBavistin®; Delsene®Derosal®  were among the pesticides found in brewed cups of tea from Lipton, Twinings, Tetley and Uncle Lee's Legends of China found in Canada.

The Tea Association of Canada and the respective brands defended their products and tea in general, telling the CBC that pesticides are a fact of modern agriculture and that tea is safe for consumers to drink.

The pesticides used in tea continues to be a hotly contested issue. Demand for tea is still massive around the world, but the countries that produce the largest amounts of the plant may not have the regulations in place to forbid the use of certain pesticides, such as DDT, that are banned in other parts of the world.

A recent Greenpeace study highlighted that tea time is supposed to be a time to relax and regroup, but it could be one of the riskiest moments of the day. At least, that’s according to a new study released by Greenpeace earlier this month that found a number of popular tea brands contain high doses of pesticide residues. Some teas even tested positive for the long-banned DDT.

Greenpeace published two reports looking at tea in China and in India. In both accounts, the levels of pesticide residues found in tea samples were disturbingly above the safe limits set by the World Health Organization.

China and India are the first and second largest producers of tea, respectively, and a good deal of their tea is exported internationally. It's important to note that although the United States imports almost all of its tea, tea companies are required to produce documentation that proves their compliance before being approved by the FDA and customs. Greenpeace's studies focused on China and India, which are the largest producers, as well as the largest consumers, of tea. Their food safety regulations differ wildly from those of the United States.

In 49 Indian tea samples tested, nearly 60 percent contained at least one pesticide above the safety limits set by the European Union. In 18 samples, the quantity of pesticides were “50 percent more than the maximum level.” A whopping 33 samples contained DDT. In the report on China’s teas, nearly 67 percent of samples (18 total) contained pesticides that have been previously banned under the Stockholm Convention. “Richun's Tieguanyin 803 tea [from China] showed up with 17 different kinds of pesticides!” reported Greenpeace. In total, 14 samples from China contained pesticides that are known to harm unborn children or cause genetic damage.

Brands tested were from 8 of the 11 top tea brands such as Twinings, Tata Tea, Tetley, Brooke Bond, Golden Tips, Goodricke and surprisingly, the No. 1 tea brand: Lipton. In Greenpeace’s studies, three of four Lipton samples, “contained pesticides that are banned for use on tea plants and are highly toxic. Altogether 17 different kinds of pesticides were found on the four samples.”

"As the world's best-selling tea brand, Lipton is taking advantage of China's loose pesticide control measures at the expense of its Chinese customers," Wang Jing, Greenpeace food and agriculture campaigner, told Greenpeace East Asia.

Pesticides found through the test included a number of pesticides that Greenpeace reports are a result of “complicated and confusing” regulations. For instance:

“As of May 2014, a total 248 chemical pesticides have been registered under section 9(3) of the Insecticides Act (1968) for use in India, for all crops. However, the rationale for permitting these remains far from clear; for example, the list contains Endosulfan, which has been subject to a separate comprehensive ban by decision of the High Court as of 2011.”

Pesticides found included methomyl, (also sold as S-Methyl-N-[(methylcarbamoyl)oxy]thioacetimidate; Lannate®) an insecticide known for harming the nervous system; dicofol, (also sold as Kelthane (TM) ; 4.4'-Dichloro-a-[trichloromethyl]benzhydrol1.1-Bis(p-chlorophenyl)-2.2.2-trichloroethanol methomyl), a chemical related to DDT; and endosulfan among many others.

To the news of the findings, Hindustan Unilever Limited (HUL), one of the largest companies reported in the study, said it complies with the law. "We have internal HACCP (Hazard Analysis Critical Control Point) processes for all our factories,” HUL told DNA India. “Samples of raw materials and finished products are regularly sent to third-party testing laboratories. Our data does not show the presence of any unapproved chemicals and we fully comply with the Indian foods regulations as stipulated by the Food Safety and Standards Authority of India (FSSAI)."

HUL added it was looking to phase out pesticides with its suppliers by 2020.

Meanwhile, the Tea Board of India is questioning the studies, saying the trace levels of chemicals came from plantations outside the soils.

Another claim? Peter Goggi, president of the Tea Association of the United States, says the pesticides can remain in the soils long after they're used. "If you look at ag-reports and certain papers that are done, residual DDT is still there," he told AlterNet. He says that although Greenpeace may have pointed out pesticides, the report fails to prove the tea is unsafe to consume. "The tea is safe to consume and as a tea association we work in partnership work with growers and FDA to work with the entire supply."

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Coulomat E Reagent for Karl Fisher Titration Honeywell Hydranal ™ | Greyhound Chromatography

Honeywell Coulometry Reagents for Karl Fischer Titration

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HONEYWELL PRODUCT LISTING

Honeywell Hydranal ™ Coulomat E Reagent for Karl Fisher Titration

CAS NO: NOT APPLICABLE

 

Anolyte for coulometric Karl Fischer titration (ethanol-based), for cells with and without diaphragm

 

Synonym(s)
Ethyl Alcohol
Honeywell Hydranal ™ Water Standards Hydranal Coulomat E Reagent for Karl Fischer

 Advantages of Hydranal Coulometric Reagents

  • Easy to use
  • High accuracy for trace amounts of water
  • Stable conditions of the titration vessel
  • Broad product range
  • Long shelf life (up to five years)

Specifications

 

Property   Value
Suitability for KF Titration   test passed
Water (Karl Fischer)   5-50 ppm

 

Properties  

Property   Value
Boiling Point/Range     67°C 
Colour     Yellowish to Brownish, Clear
Density     0.980 g/cm3 (20°C)
Flashpoint     12°C
For Use With (Equipment)     KF Titration
Form     Liquid
Grade     Coulometric KF Reagents
Incompatible Materials  
  Oxidising Agents
Lower Explosion Limit     Not determined
Melting Point/Range     No data available
Partition Coefficient     No data available
Product Line     Hydranal ™
Solubility in Water     Completely miscable
Storage temperature     Ambient
Upper Explosion Limit     Not determined
Vapor Pressure     No data available
Viscosity     No data available
pH-Value     No data available

Safety Information      

GHS Classification

                                                            

GHS05 - Corrosive      GHS08 - Health Hazard        GHS07 - Harmful       GHS02 - Flammable

 

Property Value
Precautionary Statements In case of inadequate ventilation wear respiratory protection.;Wear protective gloves/protective clothing/eye protection/face protection.;Do not breathe dust/fumes/gas/mist/vapours/spray.
Hazard Class 3
Package Group II
UN ID UN1993

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Chem Service Reference Standards | Greyhound Chromatography
NEW Chem Service Reference Standards | Greyhound Chromatography
The Importance of Testing Cannabis | Chem Service Inc. | Greyhound Chromatography

THE IMPORTANCE OF TESTING CANNABIS 

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Cannabis Leaves

 

Cannabis Solvents extract the oil and can contain harmful residues. 

 

Cannabis can have many benefits and as it becomes more legalized across the United States the industry is starting to be held to quality control standards. Like any growing industry though, there is still a lot of room for growth regarding safety and testing. For example, if medical cannabis was put into the same bucket as other pharmaceuticals, every batch would be tested for potency and purity, but that is not always the case.

During the cannabis extraction process to create concentrations for recreation, food, pharmaceuticals and personal care items, solvents and other hydrocarbons can be used that contain potentially unsafe residues. Testing cannabis for both medical and recreational use varies from state to state, but it is important to test for residual solvents that can be potentially harmful to users.

What are the Active Chemicals in Cannabis?

Cannabis is derived from a complex plant called hemp, or Cannabis sativa. The most known active ingredient is THC, or delta-9-tetrahydrocannadinol, that is found in the leaves and flowering parts of the plant and is responsible for the behavioral influences of marijuana. The other common active ingredient is cannabidiol which is related to diet, energy utilization and pain sensors. The structure of the chemicals are very similar, but their effects are quite different.

What are Cannabis Oil Solvents?

When utilizing a solvent to extract cannabis oil it is intended to evaporate, but sometimes the evaporation process does not remove all of the solvent and it remains in the final product. Solvents are separated into 3 categories: Class 1 (volatile solvents to avoid), Class 2 (suspect solvents to limit) and Class 3 (safe solvents to use).

Some common residual solvents to test for include:

Acetone (Class 3) Heptane (Class 3)
Acetonitrile (Class 2) Methanol (Class 2)
Benzene (Class 1) Pentane (Class 3)
Chloroform (Class 2) Toluene (Class 2)
Ethanol (Class 3) Triethylamine (Class 1)

Can you Make Cannabis Oil Without Solvents?

There are many ways to make cannabis oil without the use of harmful solvents. A solventless, or mechanical extraction, can be used and does not require chemicals to achieve the final product. When small hair-like growths (trichomes) are rubbed or pressed from the plant, it results in a concentrate known as kief. Ice water extraction can also be using to make kief which is then pressed into bubble hash. These processes leave more of the original cannabinoids intact that are normally altered from the use of solvents and can be tried safely at home.

What is a Cannabinoid Profile?

Cannabinoids are chemical compounds produced by cannabis flowers that mimic the effects of endocannabinoids. These chemicals are naturally produced in the human body to help us maintain homeostasis.

A cannabinoid profile informs consumers about the concentration of active cannabinoids in their product. Cannabinoids can help with a variety of things such as pain, nausea relief, preventing nervous system degeneration, and reducing seizures and convulsions, so this profile aids processors, physicians and consumers in understanding the potency of cannabis products and when assessing which product is best suited for the patient’s needs.

How do you Test Cannabis Oil?

There are no strong regulations or guidelines currently in place about how cannabis is tested and measured making it even more important to test cannabis at home. To get an accurate determination of solvent residuals in a cannabis sample a chromatography should be used. This test provides high accuracy that users can depend on.

Analyzing Cannabinoids using Chromatography

Chromatography plays a vital role in the purification and testing of cannabis products and can be tightly linked to cannabis safety. This testing process is helpful to accurately measure the levels of cannabinoids and terpenes while also checking for potential contaminants such as pesticides, heavy metals, and residual solvents.

Chem Service Provides Residual Solvents for Testing the Safety of Cannabis

Chem Service has recently launched residual solvents that test the safety of cannabis products. Through our years of experience with chemical testing, we have curated residual solvent mixes for those across the United States and additionally for those who live in California, Oregon, Florida, and Canada.

Click over to our ‘Residual Solvents’ page for more information on the Chem Service options or call our seasoned staff at 1-800-452-9994 to discuss any questions you may have and how we can best help with your needs.

Sources

About Chem Service Inc

  Chem Service Logo Image

Established in 1962 Chem Service is the largest independent supplier of Analytical Reference Materials and the original source of small quantities of organic chemicals. Chem Service also has over 2,000 Pesticide Standards, including Pesticide Standards for Cannabis in its catalogue.  Chem Service offers Custom made Standards manufactured to your specific requirements, all standards are accredited to ISO 17043:2016; ISO/IEC 17025:2005; ISO 9001:2015 Quality Management System.

Over 95% of Chem Services’ neat Standards Grade materials have a purity of 98.0% or greater.

Chem Services’ worldwide customers are found in the chemical, government, food quality, agricultural and life science research communities.

 

Chem Service Products

 View Chem Service's ISO Accreditations and Certifications

Chem Service, Inc. is a leader in the design, development, production, distribution, and servicing of organic neat and synthetic reference materials and has achieved multiple industry certifications:

   

Chem Service Accreditation Logos      

 Environmental Reference Standards 

  • Arochlors
  • Azodyes
  • Bisphenols  Learn More
  • Cannabis Testing Standards (Individual US States) Learn More
  • Carbohydrates
  • Carbon 13, Deuterated Standards
  • Conazoles Learn More
  • custom Solutions & Mixtures
  • Dyes  Learn More
  • Explosives                 Learn More
  • Hexachlorocyclopentadiene Learn More
  • Inorganic Reference Standards
  • Neonicotinoids  Learn More
  • Organic Reference Standards
  • Oxidisers
  • PBB's
  • PBDE's Learn More
  • PCB's
  • Pesticides/Metabolites (including Conazole Fungicides, Cannabis Pesticide Standards)
  • Phthalates  Learn More
  • Plasticizers
  • Polybromodiphenyl Ethers
  • Residual Solvent Standard Mixtures for Cannabis Testing  Learn More 
  • Surfactants
  • Terpenes Learn More
  • Vitamin Reference Standards  Learn More

 EPA Standards Mixtures

  •  Methods 500 - 8000
  • CLP (Contract LAboratory Programme)
  • TPH (Total Petroleum Hydrocarbons)
  • UST (UNderground Storage Tanks)

International Standard Mixtures 

  • Canadian Regulation Standards
  • European Regulation Standards
  • ISO Standards
  • DIN Standards Learn More 

USP Methods 561: Chlorinated Pesticides, Phosphorus Pesticides, Pyrethroids Kits Learn More

  

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