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Blog posts tagged with 'anisoles'

Bee Population Pesticide Research | Chem Service Reference Standards | Greyhound Chromatography
Bee Population Pesticide Research | Chem Service Reference Standards | Greyhound Chromatography
DROŠĪBAS DATU LAPA Latvian MSDS Now Available | Chem Service
DROŠĪBAS DATU LAPA Latvian MSDS Now Available Chem Service Products
Are Pesticides Used On Bananas | Chem Service | Greyhound Chromatography

Why do bananas require so many pesticides?

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Bananas are the most popular fruit in the world. About 115 million tons of bananas are consumed each year, produced in more than 100 countries. Americans eat more bananas than any other fruit, consuming 6.4 billion bananas a year on its own, with every American each eating an average of 10 pounds per year.

Despite this massive demand for bananas, the sweet fruit cannot be grown in the U.S. The burden of supplying the global banana hunger falls on countries in the tropics, including Costa Rica, India, Brazil, Ecuador and many others. Although these countries have excellent climates for growing bananas, they also breed a variety of pests and fungi that can wreak havoc on this popular crop.

The chief of sustainable agriculture for the nonprofit organization Rainforest Alliance Chris Willie talked to NPR's All Things Considered about how the climate presents a variety of dangers to banana harvesting. He explained that the warm, humid, remote plantations are prone to the growth of an airborne fungus called Black Sigotoka. This growth can destroy an entire plantation in about a week – a costly problem for this profitable fruit.

Worms, fruit-hungry insects and tree diseases are also common problems in banana plantations, Willie told NPR. To combat these risk factors, most banana farmers and fruit companies turn to a cocktail of pesticides that can help reduce the damage from each of the banana's many enemies. Examine some the most common pesticides used on banana plantations to understand the industry better, whether as a researcher or consumer.


Chlorpyrifos - An insecticide, acaricide and miticide, chlorpyrifos is an organophosphate used on many crops throughout the world. Although formerly used as a household insecticide, the Environmental Protection Agency has placed many restrictions on the product, which has been found to have negative effects on those who use the chemical compound. Chlorpyrifos, chemically written as C9H11Cl3NO3PS, has been in use for more than 40 years and is seen by some as a smart alternative to pesticides that kill beneficial insects.


Thiabendazole – ​Thiabendazole, also known as the medications Mintezol and Tresaderm, is a fungicide and parasiticide that is used on banana planatations. Its chemical formula is C10H7N3S. Thiabendazole is the most common pesticide residue found in bananas, occuring in 48.1 percent of the bananas tested, according to the Pesticide Action Network North America. Although banana farmers use particularly high amounts of pesticides, with the Environmental Working Group putting the number at 35 pounds per acre, the residues aside from thiabendazole are particularly low because the banana peel protects the edible portion from many chemicals.


Azoxystrobin - Azoxystrobin is also a fungicide, used for a variety of produce farming. Known by commercial names including Amistar and Heritage, azoxystrobin is effective against multiple fungi such as powdery mildew, late blight, apple scab and rusts. Absorbed through the banana tree's roots it moves through the leaves to keep fungus at bay. Referred to as Methyl (E)-2-{2-[6-(2-cyanophenoxy) pyrimidin-4-yloxy]phenyl}-3-methoxyacrylate), azoxystrobin has a low toxicity to most avian, aquatic and terrestrial animals.


Imidacloprid - Imidacloprid is a neonicotinoid, which acts as a neurotoxic insecticide. This chemical compound, 1-(6-chloro-3-pyridylmethyl)-N-nitroimidazolidin-2-ylideneamine, can be used as a seed treatment or applied topically, and is effective against soil, chewing and sucking insects, according to the National Pesticide Information Center, a joint body between the EPA and Oregon State University.

Complications of pesticides in banana plantations

Although most growers see pesticide use as critical to the success of banana farming, critics point to the detrimental effects that these chemical compounds have had on animals near the plantations, such as crocodiles in Costa Rica. Fish have died in large numbers as well.  Specialists work with banana plantations to reduce the amount of pesticides used and introduced to the wild life through improper use.

Author:  Chris Boyd, Chem Service Inc  August 2014

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Phenamacril Pesticide Reference Standard | Chem Service | Greyhound Chromatography

Phenamacril Pesticide Reference Standard

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Also Available: 

Dinoterb Herbicide Reference Standard

 

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Beflubutamid Pesticide Reference Standard | Chem Service | Greyhound Chromatography
NEW Beflubutamid Pesticide Reference Standard | Chem Service Inc. | Greyhound Chromatography
Phthalate Reference Standards | Chem Service | Greyhound Chromatography

Phthalate Reference Standards 

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Phthalates are a group of compounds that are primarily used as vinyl softeners. They provide flexibility and durability to plastics that are used in many industrial and consumer products, including children’s toys, food packaging, medical devices, building materials and personal care items.

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Phthalate Reference Standards

 

Chem Service also has over 2,000 Pesticide and Metabolite Reference Standards.

 

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About the Author

Susan MAssie, Marketing Director Greyhound Chromatography Image

Susan Massie, Sales & Marketing Director, Greyhound Chromatography and Allied Chemicals Email: sue@greyhoundchrom.com

Susan Massie is the Sales & Marketing Director for Greyhound Chromatography and Allied Chemicals, affectionately known as 'Greyhound' in our scientific community. Greyhound was founded by Susan's husband Paul Massie more than 40 years ago, Susan hasn't been in the business for all of that time but has been involved with Greyhound for over 17 years. Greyhound continues to grow, expanding into new markets and taking on the challenges of our ever changing environment. It's heartwarming to witness the world waking up to the fact that we are damaging our planet on a daily basis. Every action we take has a direct effect on our planet and the world we leave behind for future generations. Susan is passionate about climate change and is happy to work in an industry that can have a direct effect on reducing the impact of our actions on the environment. All of the team at Greyhound take our responsibilities very seriously, the products that we supply are used by the world's leading scientists and chemists as they endeavour to monitor and repair the environment. All is not lost, if we all take responsibility for our actions, from reducing our waste and reusing or recycling our material collateral we can make a difference. The internet is full of useful advice and guidance, Susan is proud to contribute to that wealth of knowledge whenever she can.

Greyhound prides itself on personal service which provides prompt, efficient, cost-effective, safe delivery of all products. Greyhound provides technical advice and distribution of Certified Reference Standards and Materials, Laboratory Consumables, Solvents and Reagents across all scientific disciplines. Greyhound Chromatography offers over 1 Million products from its UK warehouse. The team at Greyhound are proud to support the work of the world's leading scientists and chemists as they challenge the abuse of our planet and try to make a difference to the world we leave behind for our ancestors.

You can view Susan's Linked In Profile here https://www.linkedin.com/in/susan-massie-79ab4121/

 

 

2,2',4,5,6'-Pentabromodiphenyl Ether (BDE 102) | Chem service | Greyhound Chromatography

NEW Chem Service product

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2,2',4,5,6'-Pentabromodiphenyl ether(BDE 102) Solution 50ug/mL in Isooctane

available now 

Chem Service Certified Reference Standards

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Established in 1962 Chem Service is the largest independent supplier of Analytical Reference Materials and the original source of small quantities of organic chemicals. Chem Service also has over 2,000 Pesticide Standards, including Pesticide Standards for Cannabis in its catalogue.  Chem Service offers Custom made Standards manufactured to your specific requirements, all standards are accredited to ISO 17043:2016; ISO/IEC 17025:2005; ISO 9001:2015 Quality Management System.

Over 95% of Chem Services’ neat Standards Grade materials have a purity of 98.0% or greater.

Chem Services’ worldwide customers are found in the chemical, government, food quality, agricultural and life science research communities.

Alternatively, you can view the full range of Chem Service products here - Chem Service Full product range

 

2,2',4,5,6'-Pentabromodiphenyl ether(BDE 102) Solution 50ug/mL in Isooctane

Chem Service Product

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Part #:S-14357K0-1ML
CAS: 446254-66-6
 

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Multilingual MSDS avaliable, please email us to find out more using info@greyhoundchrom.com  

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Stockholm Convention Chemicals | Wellington Laboratories | Chem Service | Greyhound Chromatography

New Listing of Chemicals: Persistent Organic Pollutants (POPs) under the Stockholm Convention

Governments agree landmark decisions to protect people and planet from hazardous chemicals and waste, including plastic waste

The two new chemicals listed in Annex A to the Stockholm Convention are the pesticide Dicofol, and Perfluorooctanoic acid (PFOA) its salts and PFOA-related compounds (some applications with time-limited exemptions). Listing in Annex A to the Convention obliges Parties to eliminate these chemicals from use. The two chemicals are listed on the basis of a robust review process addressing risks, management options and alternatives by the UN’s POPs Review Committee. Dicofol is used as a miticide on a variety of field crops, fruits, vegetables, ornamentals and tea and coffee and is known to cause skin irritation and hyperstimulation of nerve transmissions in humans as well as being highly toxic to fish, aquatic invertebrates, algae and birds. PFOA is a widely-used industrial chemical used in the production of non-stick cookware and food processing equipment, as well as a surfactant in textiles, carpets, paper, paints and fire-fighting foams. As a substance of very high concern, it is known to be linked to major health problems including kidney cancer, testicular cancer, thyroid disease and hypertension in pregnancy. More information on these chemicals is available in factsheets at: http://chm.pops.int/tabid/243/Default.aspx

View the Full article below. 

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Dicofol Pesticide Analytical Testing Standard available from Greyhound Chromatography  

 

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Full Range of Wellington Laboratories Analytical Reference Standards, including PFOAs and PFASs Available from Greyhound Chromatography  View Full Range of Products    HERE 

 

Governments agree landmark decisions to protect people and planet from hazardous chemicals and waste, including plastic waste

 

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Geneva, 10 May 2019 - Decisions on plastic waste have been reached today in Geneva, as approximately 180 governments adopted a raft of decisions aimed at protecting human health and the environment from the harmful effects of hazardous chemicals and waste.

Pollution from plastic waste, acknowledged as a major environmental problem of global concern, has reached epidemic proportions with an estimated 100 million tonnes of plastic now found in the oceans, 80-90% of which comes from land-based sources1. Governments this week amended the Basel Convention to include plastic waste in a legally-binding framework which will make global trade in plastic waste more transparent and better regulated, whilst also ensuring that its management is safer for human health and the environment. At the same time, a new Partnership on Plastic Waste was established to mobilise business, government, academic and civil society resources, interests and expertise to assist in implementing the new measures, to provide a set of practical supports – including tools, best practices, technical and financial assistance - for this ground-breaking agreement.

Other far-reaching decisions from the two weeks included the elimination of two toxic chemical groups, which together total about 4,000 chemicals, listed into Annex A of the Stockholm Convention, namely Dicofol and Perfluorooctanoic Acid (PFOA) and its salts and PFOA-related compounds. The latter has till now been used in a wide variety of industrial and domestic applications including non-stick cookware and food processing equipment, as well as a surfactant in textiles, carpets, paper, paints and fire-fighting foams.

Important progress was also made under the Rotterdam Convention, which provides a legally-binding framework for information exchange and informed decision-making in the trade of certain hazardous pesticides and industrial chemicals. Two chemicals, the pesticide phorate and the industrial chemical hexabromocyclododecane were added to Annex III of the convention, making them subject to the Prior Informed Consent (PIC) Procedure, through which countries can decide on future imports of these chemicals. A further decision, to approve procedures and mechanisms on compliance with the Rotterdam Convention – seen as a crucial step for further improving implementation of this key convention - was adopted with great appreciation by Parties.

Working for two weeks in Geneva under the theme of “Clean Planet, Healthy People: Sound Management of Chemicals and Waste”, approximately 1,400 delegates from around 180 countries converged for the meetings of the Conferences of Parties to the Basel, Rotterdam and Stockholm conventions (Triple COPs). Participants benefited from the numerous opportunities and events to exchange information on alternatives to these chemicals, as well as best practices.

Speaking at the closing session of the Triple COPs, Rolph Payet, Executive Secretary (UNEP) of the three conventions, said that “I’m proud that this week in Geneva, Parties to the Basel Convention have reached agreement on a legally-binding, globally-reaching mechanism for managing plastic waste. Plastic waste is acknowledged as one of the world’s most pressing environmental issues, and the fact that this week close to 1 million people around the world signed a petition urging Basel Convention Parties to take action here in Geneva at the COPs is a sign that public awareness and desire for action is high.

We were able to list two out of 7 candidate chemicals and will continue working closely with parties to identify feasible alternative solutions to hazardous pesticides, taking due account of food security and market access aspects” added Hans Dreyer, Executive Secretary (FAO) of the Rotterdam Convention.

Notes for Editors:

The Basel Convention on the Control of Transboundary Movements of Hazardous Waste and their Disposal is the most comprehensive international environmental agreement on hazardous and other wastes and is almost universal, with 187 Parties. With an overarching objective of protecting human health and the environment against the adverse effects of hazardous wastes and other wastes, its scope covers a wide range of wastes defined as “hazardous” based on their origin and/or composition and characteristics, as well as two types of wastes defined as “other wastes” – household waste and incinerator ash. See www.basel.int

Plastic Waste

With an estimated 100 million tonnes of plastic in our seas, 80-90% of which has come from land-based sources, the high public profile of this issue is understandable. Reducing waste generation at source, and improving waste management thereafter, would go a long way towards solving this problem. For more on this see:  http://www.brsmeas.org/?tabid=4332&blogId=5169 and http://www.brsmeas.org/tabid/7656/Default.aspx

The Rotterdam Convention on the Prior Informed Consent Procedure (PIC) for Certain Hazardous Chemicals and Pesticides in International Trade, is jointly administered by the United Nations Food and Agriculture Organization (FAO) and UN Environment (UNEP). The 161 Parties to this legally-binding Convention share responsibility and cooperate to safely manage chemicals in international trade. As of the end of this COP, 52 chemicals and pesticides are listed in its Annex III. The Convention does not introduce bans but facilitates the exchange of information among Parties on hazardous chemicals and pesticides, and their potential risks, to inform and improve national decision making. In addition, through the PIC Procedure, it provides a legally-binding mechanism to support national decisions on the import of selected chemicals and pesticides in order to minimize the risk they pose to human health and the environment. See www.pic.int

 

Plastic Contaminating the Sea Image

Listing of Chemicals: Pesticides and Industrial Chemicals under the Rotterdam Convention

The newly-listed chemicals are phorate (a pesticide) and hexabromocyclododecane (an industrial chemical) these chemicals would be included in the prior informed consent (PIC) procedure enabling better-informed decision-making on the trade in chemicals, thereby protecting human health and the environment. More information on these chemicals is available at: http://www.pic.int/tabid/1185/Default.aspx

The Stockholm Convention on Persistent Organic Pollutants is a global treaty to protect human health and the environment from chemicals that remain intact in the environment for long periods, become widely distributed geographically, accumulate in the fatty tissue of humans and wildlife, and have harmful impacts on human health or on the environment. Exposure to Persistent Organic Pollutants (POPs) can lead to serious health effects including certain cancers, birth defects, dysfunctional immune and reproductive systems, greater susceptibility to disease and damage to the central and peripheral nervous systems. The Convention requires its Parties to take measures to eliminate or reduce the release of POPs into the environment. As of today, this legally-binding Convention has 182 Parties, giving it almost universal coverage. As of the end of this COP, 30 chemicals of global concern are listed under the Stockholm Convention. See www.pops.int

Listing of Chemicals: Persistent Organic Pollutants (POPs) under the Stockholm Convention

The two new chemicals listed in Annex A to the Stockholm Convention are the pesticide Dicofol, and Perfluorooctanoic acid (PFOA) its salts and PFOA-related compounds (some applications with time-limited exemptions). Listing in Annex A to the Convention obliges Parties to eliminate these chemicals from use. The two chemicals are listed on the basis of a robust review process addressing risks, management options and alternatives by the UN’s POPs Review Committee. Dicofol is used as a miticide on a variety of field crops, fruits, vegetables, ornamentals and tea and coffee and is known to cause skin irritation and hyperstimulation of nerve transmissions in humans as well as being highly toxic to fish, aquatic invertebrates, algae and birds. PFOA is a widely-used industrial chemical used in the production of non-stick cookware and food processing equipment, as well as a surfactant in textiles, carpets, paper, paints and fire-fighting foams. As a substance of very high concern, it is known to be linked to major health problems including kidney cancer, testicular cancer, thyroid disease and hypertension in pregnancy. More information on these chemicals is available in factsheets at: http://chm.pops.int/tabid/243/Default.aspx

For BRS conventions general media enquiries see: www.brsmeas.org or contact:
Charlie AVIS, Public Information Officer (UN Environment), Geneva 
+41-79-730-4495

 Full article courtesy of www.brsmeas.org

 

 


1 Data from “Marine litter plastics and microplastics and their toxic chemicals components: the need for urgent preventive measures” by Frederic Gallo et. al. in Environmental Sciences Europe 2018; 30(1): 13, at: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5918521/

 

 

 

You May Also be Interested in

New Branched Perfluoroalkyl Reference Standards

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It is well documented that many environmental samples contain both branched and linear isomers of perfluoroalkyl carboxylic acids and perfluoroalkanesulfonate salts.  In response to customer requests for quantitative reference standards for these compounds, wellington Laboratories has synthesized additional branched perfluoroalkyl compounds (P3MHpA, P4MOA, and NaP3MHpS) to complement their currently available selection of standards.  A typical commercial sample of perfluorooctanesulfonic acid (PFOS) contains 5% and 11% of NaP3MHpS and NaP6MHpS respectively.  Similarly, technical mixtures of perfluorooctanoic acid (PFOA) contain approximately 3% of P3MHpA.  It is hoped that the continued introduction of certified branched perfluoroalkyl reference standrds will aid researchers in the analysis of these compounds in environmental and biological samples.

Wellington Laboratories Extract

Wellington Reporter May 2019

Wellington Reporter Discontinued Products | Greyhound Chromatography

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PRODUCT DISCONTINUED

P44DMHxS

Unfortunately, P44DMHxS (a mixture of perfluoro-4-4-dimethylhexane sulfonate and perfluoro-4-4-dimethylhexanoic acid) is being discontinued due to limited interest and a lack of inventory. However, these compounds are identified as minor components in our br-PFOSK/T-PFOS and T-PFOA reference standards respectively. We apologize for any inconvenience this may cause and appreciate your understanding. 

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About Wellington Laboratories

For Over 35 years Wellington Laboratories Inc. has been internationally recognised as a trusted source of high quality reference standard solutions for use in environmental/analytical testing and toxicological research. Wellington Laboratories offers an extensive inventory of individual certified reference standards and solution mixtures of native and mass-labelled halogenated organic compounds including polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, polychlorinated biphenyls, halogenated flame retardants and perfluorinated compounds. Wellington Laboratories also offer a variety of calibration sets and support solutions designed to be used for common regulatory methods or modified in-house methods.

Wellington’s Reference Standards are used mainly in Environmental/analytical testing and toxicological research. Wellington offers an extensive inventory of individual certified reference standards and solution mixtures of native and mass-labelled halogenated organic compounds including polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, polychlorinated biphenyls, halogenated flame retardants and perfluoronated compounds. Wellington also offer a variety of calibration sets and support solutions designed to be used for common regulatory methods of modified in-house methods.

Wellington Laboratories are committed to the distribution of quality products as well as the maintenance of excellent customer service. In fact, in order to provide your customers with the best possible service, Wellington have three ISO certifications (ISO 9001:2008, ISO/IEC 17025:2005, and ISO Guide 34:2009) which cover all aspects of planning, production, testing, distribution, and post-distribution service. These certifications allow Wellington Laboratories to monitor and maintain the highest level of quality and service and also allow their customers to satisfy the requirements of their own ISO certifications.

Wellington’s ISO/IEC 17025:2005 accreditation has been certified by the Canadian Association for Laboratory Accreditation Inc. (CALA) the scope is available for review on the CALA Directory of Accredited Laboratories (http://www.cala.ca).

Similarly, Wellington’s ISO Guide 34:2009 accreditation has been certified by ANSI-ASQ National Accreditation Board (ANAB), the certificate and scope are available on their website (http://anab.org/).

We are able to supply hard copies of any of the ISO certificates for yourself and your customers.

 

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4-(Trifluoromethyl) nicotinic acid Reference Standard | Chem Service | Greyhound Chromatography the UK's Leading Chromatography Supplier

4-(Trifluoromethyl) nicotinic acid Reference Standard 

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4-(Trifluoromethyl) nicotinic acid
Alternative Names: TFNA (FLONICAMID METABOLITE), 4-(TRIFLUOROMETHYL)NICOTINIC ACID
Product Code: MET-11976A-100MG

Triclosan
Alternative Names: TFNA (FLONICAMID METABOLITE), 4-(TRIFLUOROMETHYL)NICOTINIC ACID'
Product Code: N-13076-100MG

Metamifop
Product Code: N-13084-25MG

Fthalide
Product Code: N-13085-10MG

Triclosan Solution
Product Code: S-13076M1-1ML

2,2',4,4',6-Pentabromodiphenyl Ether BDE-100 Solution
Product Code: S-13123K0-1ML

2,2',3,4,4',5,6-Heptabromodiphenyl Ether (BDE-181) Solution
Product Code: S-13128K0-1ML

What's New from Chem Service 

Chem Service Certified Reference Standards

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Established in 1962 Chem Service is the largest independent supplier of Analytical Reference Materials and the original source of small quantities of organic chemicals. Chem Service also has over 2,000 Pesticide Standards, including Pesticide Standards for Cannabis in its catalogue.  Chem Service offers Custom made Standards manufactured to your specific requirements, all standards are accredited to ISO 17043:2016; ISO/IEC 17025:2005; ISO 9001:2015 Quality Management System.

Over 95% of Chem Services’ neat Standards Grade materials have a purity of 98.0% or greater.

Chem Services’ worldwide customers are found in the chemical, government, food quality, agricultural and life science research communities.

 

Pesticide Reference Standards recently added to our website: 

2,3',4',5-tetrabromodiphenyl ether(BDE 70) Solution (CAS # 446254-39-3)

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BUY HERE

Part #:S-14273K0-1ML
CAS: 446254-39-3 

o,o,o-Tripropyl thiophosphate (CAS # 2272-08-4)

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BUY HERE 

Part #:MET-11103A-25MG
CAS: 2272-08-4

 

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BUY HERE

Part #:N-14272-50MG
CAS: 304911-98-6

2,6-Dibromobiphenyl ether (BDE 10) Solution (CAS# 51930-04-2)

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BUY HERE

Part #:S-14271K0-1ML
CAS: 51930-04-2
Classification: Polybrominated diphenyl ether
Uses: Flame retardant 
 
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Part #:MET-11963F-50MG
CAS: 56236-69-2
 

Oxathiapiprolin (CAS# 1003318-67-9)

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BUY HERE

Part Number : N-14266-10MG

CAS#:  1003318-67-9

Chemical formula: C24H22F5N5O2S

Pesticide type: Fungicide

Substance group: Piperidinyl thiazole isoxazoline

Mode of action: Systemic, preventative with residual disease control. It acts via an oxysterol binding protein.

2-Bromodiphenyl ether (BDE 1) Solution (CAS# 7025-06-1) 

Chemical Structure Image BUY HERE

Part #:S-14267K0-1ML
CAS: 7025-06-1
Empirical Formula:  C12H9BrO
Molecular Weight: 249.10

 

Chlorantraniliprole (CAS # 500008-45-7) 

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BUY HERE 

Part #: N-11422-25MG 

Cas: 500008-45-7 

Molecular Formula: C18H14BrCl2N5O2 

Pesticide type: Insecticide 

Substance group: Anthranilic diamide 

Mode of action: Exhibits larvicidal activity as an orally ingested toxicant by targeting and disrupting the Ca2+ balance; Ryanodine receptor (Group 28)

Chlorantraniliprole Solution (CAS # 500008-45-7)

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BUY HERE

Part Number: S-11422A1-1ML

Cas: 500008-45-7

 

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Phorate oxon sulfone Reference Standard (CAS# 2588-06-9) | Chem Service | Greyhound Chromatography
Phorate oxon sulfone (CAS# 2588-06-9) Chem Service Inc Certified Reference Standards Supplied by Greyhound Chromatography